I recommend you use the same firmware (setup_mb6582.asm/setup_mb6582.hex) for all PICs which will have the default set to the 8580/6582 range, and then for the slave that has 6581, change the range for just that SID, in all ensembles.
If you could be bothered, you could hard-code the default range so all ensembles would initialize with the 6581 range for one SID pair, but then you’d have to manage this difference every time TK does a new release.